Remote Publishing only works for Author-it builds from 6.4.1.35623.
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Install the Author-it Service Manager on the publishing server.
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Make sure that Author-it Service has started and runs under a dedicated user, e.g. aitservice.
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Make sure that this dedicated user has full permissions on the publishing server (local admin).
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Open Author-it Service Manager.
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Configure and start 'Publishing' for your Author-it library.